The structure of a cyclohexane sorption complex of partially dehydrated, fully Mn²⁺-exchanged zeolite Y has been determined at 100(1) K by single-crystal synchrotron X-ray diffraction techniques. It was refined using all intensities to the final error indices R₁ = 0.052 and wR₂ = 0.174. Cyclohexane molecules of symmetry $\overline{3}$2/m (D_3d, chair form) occupy 5.7 of the 16 12-rings per unit cell. Each cyclohexane molecule is held in place by 18 weak hydrogen bonds between its six equatorial hydrogen atoms and all 12 oxygen atoms of its 12-ring: C⋯O ca. 3.85 Å. Mn²⁺ ions are found at four crystallographic sites, I, I′, II′, and II. Each of the 17.7(2) Mn²⁺ ions per unit cell at site II (opposite 6-rings in the supercage) coordinates tetrahedrally to three framework oxygen atoms and a water molecule. The cyclohexane molecules interact neither with the Mn²⁺ ions nor with the water molecules.

已通过单晶同步加速器X射线衍射技术在100（1）K下确定了部分脱水，完全Mn ²⁺交换的沸石Y的环己烷吸附复合物的结构。使用所有强度将其精炼为最终误差指数R ₁  = 0.052和wR ₂  = 0.174。对称的环己烷分子$\overline{3}$2 / m（D _3d，椅子形式）占每个单元格16个12环中的5.7。Ç⋯○：每环己烷分子在适当的位置通过其六个赤道氢原子和其12环的所有12个氧原子间18个弱氢键保持CA。3.85Å。在I，I'，II'和II的四个晶体学位置发现了Mn ²⁺离子。站点II（超级笼中的6个环的对面）处每个单元格中的每个17.7（2）Mn ²⁺离子均以四面体形式与三个骨架氧原子和一个水分子配位。环己烷分子既不与Mn ²⁺离子也不与水分子相互作用。