Recent Advances in Micro‐/Nanostructured Metal–Organic Frameworks towards Photonic and Electronic Applications,Chemistry - A European Journal

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Recent Advances in Micro‐/Nanostructured Metal–Organic Frameworks towards Photonic and Electronic Applications
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-01-16 , DOI: 10.1002/chem.201704650
Xiaogang Yang ₁ , Xianqing Lin ₂ , Yong Sheng Zhao ₂ , Dongpeng Yan ₁

Affiliation

Micro‐ and nanometer‐sized metal–organic frameworks (MOFs) materials have attracted great attention due to their unique properties and various potential applications in photonics, electronics, high‐density storage, chemo‐, and biosensors. The study of these materials supplies insight into how the crystal structure, molecular components, and micro‐/nanoscale effects can influence the performance of inorganic–organic hybrid materials. In this Minireview article, we introduce recent breakthroughs in the controlled synthesis of MOF micro‐/nanomaterials with specific structures and compositions, the tunable photonic and electronic properties of which would provide a novel platform for multifunctional applications. Firstly, the design strategies for MOFs based on self‐assembly and crystal engineering principles are introduced. Attention is then focused on the methods of fabrication of low‐dimensional MOF micro‐/nanostructures. Their new applications including two‐photon excited fluorescence, multi‐photon pumped lasing, optical waveguides, nonlinear optical (NLO), and field‐effect transistors are also outlined. Finally, we briefly discuss perspectives on the further development of these hybrid crystalline micro‐/nanomaterials.

中文翻译：

微/纳米结构金属有机框架在光子和电子应用中的最新进展

微米和纳米级的金属有机框架（MOFs）材料因其独特的性能以及在光子学，电子学，高密度存储，化学和生物传感器中的各种潜在应用而受到了广泛的关注。这些材料的研究提供了有关晶体结构，分子成分和微纳尺度效应如何影响无机-有机杂化材料性能的见解。在此Minireview文章中，我们介绍了具有特定结构和组成的MOF微/纳米材料的受控合成的最新突破，其可调谐的光子和电子特性将为多功能应用提供一个新颖的平台。首先，介绍了基于自组装和晶体工程原理的MOF的设计策略。然后将注意力集中在低维MOF微米/纳米结构的制造方法上。还概述了它们的新应用，包括双光子激发荧光，多光子泵浦激射，光波导，非线性光学（NLO）和场效应晶体管。最后，我们简要讨论了关于这些杂化晶体微/纳米材料进一步发展的观点。

更新日期：2018-01-16

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