NHPI- and TBAI-Co-Catalyzed Synthesis of Allylic Esters from Toluene Derivatives and Alkenes,Synlett

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NHPI- and TBAI-Co-Catalyzed Synthesis of Allylic Esters from Toluene Derivatives and Alkenes
Synlett ( IF 1.7 ) Pub Date : 2018-01-15 , DOI: 10.1055/s-0036-1591748
Hongmei Deng ₁ , Xueshun Jia _{2,

3} , Jian Li _{2,

3} , Chengliang Li ₂ , Tao Jin ₃ , Chunju Li ₃

Affiliation

An N-hydroxyphthalimide (NHPI) and tetrabutylammonium iodide (TBAI) co-catalyzed oxidative coupling reaction of toluene derivatives and alkenes has been disclosed. This method can serve as a new strategy to access allylic ester using toluene derivatives as oxyacylating reagent. This metal-free protocol also features the readily available starting materials, broad substrate scope, and mild reaction conditions.

中文翻译：

NHPI-和TBAI-Co-催化从甲苯衍生物和烯烃合成烯丙酯

已经公开了 N-羟基邻苯二甲酰亚胺 (NHPI) 和四丁基碘化铵 (TBAI) 共催化的甲苯衍生物和烯烃的氧化偶联反应。该方法可以作为使用甲苯衍生物作为氧酰化试剂获得烯丙酯的新策略。这种无金属协议还具有易于获得的起始材料、广泛的底物范围和温和的反应条件。

更新日期：2018-01-15

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