Trifluoroethoxy-Coated Subphthalocyanines Attract Small Arenes in Their π-Concave Cavity.,ChemPlusChem

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Trifluoroethoxy-Coated Subphthalocyanines Attract Small Arenes in Their π-Concave Cavity.
ChemPlusChem ( IF 3.0 ) Pub Date : 2018-01-15 , DOI: 10.1002/cplu.201800004
Satoru Mori ₁ , Jiandong Wang ₁ , Etsuko Tokunaga ₁ , Motoo Shiro ₂ , Takashi Matsumoto ₂ , Seiji Tsuzuki ₃ , Norio Shibata _{1,

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Affiliation

Invited for this month's cover is the group of Prof. Norio Shibata based at the Nagoya Institute of Technology, Japan. The cover picture shows the crystal structures of trifluoroethoxy-substituted subphthalocyanines which form crystalline clathrates with one small aromatic molecule, such as toluene or benzene, in their concave cavity. Twelve trifluoroethoxy substituents flexibly surround the small molecule to hold it on the 14π-electron conjugated surface of the subphthalocyanines. Read the full text of the article at 10.1002/cplu.201700508.

中文翻译：

三氟乙氧基涂层的亚酞菁在其π凹腔中吸引着小芳烃。

本月封面的邀请是日本名古屋工业大学的Shibata Norio教授小组。封面图片显示了三氟乙氧基取代的亚酞菁的晶体结构，它们在其凹腔中与一个小的芳香分子（如甲苯或苯）形成结晶包合物。十二个三氟乙氧基取代基可灵活围绕小分子，以将其固定在亚酞菁的14π电子共轭表面上。阅读文章全文10.1002 / cplu.201700508。

更新日期：2018-01-15

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