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Front Cover: Syntheses of Amino‐Substituted Iridabenzofurans and Subsequent Selective N‐Functionalisation (Chem. Eur. J. 17/2018)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2018-01-15 , DOI: 10.1002/chem.200706154
Benjamin J. Frogley 1 , Lakshika C. Perera 1 , L. James Wright 1
Affiliation  

The chemistry of metallabenzenes and fused‐ring metallabenzenes continues to expand. Herein, we report the first simple amino‐substituted derivatives. Remarkably, these compounds were synthesized by reduction of the corresponding nitro‐iridabenzofurans with zinc and concentrated hydrochloric acid. The amino groups are readily functionalized, with selectivity controlled by the stoichiometry of the reactants, the steric bulk of the electrophiles, and the charge on the metal. More information can be found in the Full Paper by L. J. Wright et al. on page 4304.
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中文翻译:

封面:氨基取代的铱苯并呋喃的合成及随后的选择性N功能化(Eur.J.17 / 2018)

金属基苯和稠环金属基苯的化学物质继续发展。在这里,我们报道了第一个简单的氨基取代的衍生物。值得注意的是,这些化合物是通过用锌和浓盐酸还原相应的硝基-铱-苯并呋喃而合成的。氨基容易被官能化,其选择性由反应物的化学计量,亲电体的空间体积和金属上的电荷控制。可以在L. J. Wright等人的论文全文中找到更多信息。在第4304页。
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更新日期:2018-01-15
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