Efficient Synthesis of Succinimide from Succinic Anhydride in Water over Unsupported Nanoporous Nickel Material,ChemistrySelect

当前位置： X-MOL 学术 › ChemistrySelect › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Efficient Synthesis of Succinimide from Succinic Anhydride in Water over Unsupported Nanoporous Nickel Material
ChemistrySelect ( IF 1.9 ) Pub Date : 2018-01-15 , DOI: 10.1002/slct.201703154
Yunjie Liu ₁ , Jun Fu ₁ , Dezhang Ren ₁ , Zhiyuan Song ₁ , Fangming Jin ₁ , Zhibao Huo ₁

Affiliation

The synthesis of succinimide from succinic anhydride (SA) in water over unsupported nanoporous nickel material (NiNPore) is investigated for the first time. As a result, NiNPore exhibited efficient catalytic performance for the conversion of SA into succinimide and gave 93% isolated yield. Recycling study indicated that NiNPore could be reused at least three times and still kept good catalytic activity for the transformation. Moreover, the conversion of glutaric anhydride (GA) could also proceed well into glutarimide at optimal conditions, and provided 71% isolated yield. The result indicated that SA was the main reactant rather than succinic acid in water. This work provides a promising strategy for the conversion of SA into succinimide in water.

中文翻译：

在无载体的纳米多孔镍材料上由琥珀酸酐在水中高效合成琥珀酰亚胺

首次研究了在无载体的纳米多孔镍材料（NiNPore）上由琥珀酸酐（SA）在水中合成琥珀酰亚胺。结果，NiNPore表现出有效的催化性能，可将SA转化为琥珀酰亚胺，分离产率为93％。回收研究表明，NiNPore可以重复使用至少3次，并且仍保持良好的催化活性。此外，在最佳条件下，戊二酸酐（GA）的转化也可以很好地转化为戊二酰亚胺，并提供71％的分离产率。结果表明，SA是水中的主要反应物，而不是琥珀酸。这项工作为SA在水中转化为琥珀酰亚胺提供了有希望的策略。

更新日期：2018-01-15

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11