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In Situ Growth of MnO2 Nanosheets on N‐Doped Carbon Nanotubes Derived from Polypyrrole Tubes for Supercapacitors
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2018-02-08 , DOI: 10.1002/asia.201701752
Xu Ou 1 , Qi Li 1 , Dan Xu 1 , Jiangna Guo 1 , Feng Yan 1
Affiliation  

Nitrogen‐doped porous carbon nanotubes@MnO2 (N‐CNTs@MnO2) nanocomposites are prepared through the in situ growth of MnO2 nanosheets on N‐CNTs derived from polypyrrole nanotubes (PNTs). Benefiting from the synergistic effects between N‐CNTs (high conductivity and N doping level) and MnO2 nanosheets (high theoretical capacity), the as‐prepared N‐CNTs@MnO2‐800 nanocomposites show a specific capacitance of 219 F g−1 at a current density of 1.0 A g−1, which is higher than that of pure MnO2 nanosheets (128 F g−1) and PNTs (42 F g−1) in 0.5 m Na2SO4 solution. Meanwhile, the capacitance retention of 86.8 % (after 1000 cycles at 10 A g−1) indicates an excellent electrochemical performance of N‐CNTs@MnO2 prepared in this work.

中文翻译:

在超级电容器用聚吡咯管衍生的N掺杂碳纳米管上原位生长MnO2纳米片。

氮掺杂多孔碳纳米管@MnO 2N- CNTs @ MnO 2)纳米复合材料是通过在源自聚吡咯纳米管(PNT)的N-CNT上原位生长MnO 2纳米片而制备的。由N-碳纳米管(高导电性和N掺杂水平)和MnO之间的协同效应中受益2个纳米片(高理论容量),所制备的N-碳纳米管@的MnO 2 -800纳米复合材料显示出219 F G的特定电容-1在1.0 A g -1的电流密度下,高于0.5 m内纯MnO 2纳米片(128 F g -1)和PNTs(42 F g -1) 的电流密度Na 2 SO 4溶液。同时,电容保持率为86.8%(在10 A g -1下经过1000次循环后)表明在这项工作中制备的N-CNTs @ MnO 2具有出色的电化学性能。
更新日期:2018-02-08
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