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Very efficient green light-emitting diodes based on polycrystalline CH(NH3)2PbBr3 film achieved by regulating precursor concentration and employing novel anti-solvent
Organic Electronics ( IF 3.2 ) Pub Date : 2018-01-12 , DOI: 10.1016/j.orgel.2017.12.041
Yongzhang Zhu , Xiaofei Zhao , Baohua Zhang , Bing Yao , Zhanguo Li , Yi Qu , Zhiyuan Xie

Formamidinium lead halide CH(NH3)2PbX3 (FAPbX3) perovskite materials have achieved significant progress in efficient and stable single-junction/tandem perovskite solar cells, which is due to the promising thermal and air stability features. However, successful application of these materials in perovskite light-emitting diodes (PeLEDs) is scarce. Herein, regulating the FABr:PbBr2 precursor concentration procedure is utilized to prepare very efficient PeLEDs based on CH(NH3)2PbBr3 (FAPbBr3). The resultant FAPbBr3 film prepared at optimized 10 wt% condition shows the satisfied exciton radiative rate and low nonradiative rate, and a high photoluminescent quantum yield. In combination with novel ethyl acetate (EA) anti-solvent spin-washing method, the resultant FAPbBr3 film shows compact, uniform and high coverage morphology characteristics. The PeLEDs show a maximum current efficiency of 13.4 cd A−1, an external quantum efficiency of 3.5%, a maximum luminance close to 10000 cd m−2, and an extremely high power efficiency of 19.1 lm W−1, respectively. This performance is the best among all reported on FAPbBr3 type PeLEDs.



中文翻译:

基于多晶CH(NH 32 PbBr 3薄膜的非常高效的绿色发光二极管,可通过调节前驱物浓度并采用新型抗溶剂来实现

甲ami鎓卤化铅CH(NH 32 PbX 3(FAPbX 3)钙钛矿材料在有效和稳定的单结/串联钙钛矿太阳能电池方面取得了重大进展,这归因于其有前途的热稳定性和空气稳定性。然而,这些材料在钙钛矿发光二极管(PeLED)中的成功应用很少。在本文中,调节FABr:PbBr 2前驱物浓度程序可用于制备基于CH(NH 32 PbBr 3(FAPbBr 3)的非常有效的PeLED 。所得的FAPbBr 3在优化的10wt%条件下制备的薄膜显示出满意的激子辐射速率和低非辐射速率,以及高的光致发光量子产率。结合新颖的乙酸乙酯(EA)反溶剂旋转洗涤方法,所得FAPbBr 3膜表现出致密,均匀和高覆盖的形态特征。PeLED分别显示出13.4 cd A -1的最大电流效率,3.5%的外部量子效率,接近10000 cd m -2的最大亮度和19.1 lm W -1的极高功率效率。在所有FAPbBr 3型PeLED报道中,该性能都是最好的。

更新日期:2018-01-12
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