当前位置: X-MOL 学术Catal. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Catalytic isomerization of galactose into tagatose in the presence of bases and Lewis acids
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-01-12 , DOI: 10.1016/j.catcom.2018.01.011
Peter Drabo , Irina Delidovich

Catalytic efficiency of bases and a Lewis acid for isomerization of galactose into tagatose was comparatively studied. NaH2PO4 + Na2HPO4 phosphates and Mg-Al hydrotalcite were tested as soluble and solid base catalysts. Selectivity towards tagatose over these base catalysts decreases along with galactose conversion owing to formation of sorbose as a side product. In the presence of the bases, yield of tagatose was limited to 16% obtained at 51% galactose conversion. Sn-BEA zeolite presents a solid Lewis acid. This catalyst enables a selective transformation of galactose giving rise to tagatose in 24% yield at 29% conversion of the substrate.



中文翻译:

在碱和路易斯酸存在下半乳糖催化异构化为塔格糖

比较研究了碱和路易斯酸将半乳糖异构化为塔格糖的催化效率。测试了NaH 2 PO 4  + Na 2 HPO 4磷酸盐和Mg-Al水滑石作为可溶和固体碱催化剂。由于形成副产物山梨糖,与这些半乳糖催化剂相比,对塔格糖的选择性随着半乳糖转化而降低。在碱的存在下,塔格糖的产率限于在51%半乳糖转化率下获得的16%。Sn-BEA沸石呈固体路易斯酸。该催化剂能够选择性转化半乳糖,从而以24%的收率生成塔格糖,而底物的转化率为29%。

更新日期:2018-01-12
down
wechat
bug