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Multiwalled Carbon Nanotubes Anode in Lithium-Ion Battery with LiCoO2, Li[Ni1/3Co1/3Mn1/3]O2, and LiFe1/4Mn1/2Co1/4PO4 Cathodes
ACS Sustainable Chemistry & Engineering ( IF 7.1 ) Pub Date : 2018-01-11 00:00:00 , DOI: 10.1021/acssuschemeng.7b03395
Daniele Di Lecce 1 , Paolo Andreotti 1 , Mattia Boni 1 , Giulia Gasparro 1 , Giulia Rizzati 1 , Jang-Yeon Hwang 2 , Yang-Kook Sun 2 , Jusef Hassoun 1
Affiliation  

Multiwalled carbon nanotubes (MWCNTs) are studied for the first time as the anode in lithium-ion batteries using LiCoO2, Li[Ni1/3Co1/3Mn1/3]O2, and LiFe1/4Mn1/2Co1/4PO4 cathodes. The anode material has a partially graphitic structure and nanotube morphology, which ensure stable cycling, Coulombic efficiency exceeding 99% as well as remarkable rate-capability in lithium half-cell, and suggest the compatibility for full-cell application. The performance of each lithium-ion array appears strongly related to the different structural, morphological and electrochemical features of the positive electrodes. The study in full-cell of the MWCNTs anode, to date mostly investigated in lithium half-cell, is therefore performed under various conditions. The MWCNTs/Li[Ni1/3Co1/3Mn1/3]O2 combination reveals promising behavior in terms of cycling stability, reversible capacity and Coulombic efficiency, which well demonstrates the potential suitability of MWCNTs as anodes in lithium-ion cell.

中文翻译:

具有LiCoO 2,Li [Ni 1/3 Co 1/3 Mn 1/3 ] O 2和LiFe 1/4 Mn 1/2 Co 1/4 PO 4阴极的锂离子电池中的多壁碳纳米管阳极

首次研究了使用LiCoO 2,Li [Ni 1/3 Co 1/3 Mn 1/3 Mn ] / 2和LiFe 1/4 Mn 1 /作为锂离子电池中阳极的多壁碳纳米管(MWCNTs)。2 Co 1/4 PO 4阴极。负极材料具有部分石墨结构和纳米管形态,可确保稳定的循环,库伦效率超过99%以及在锂半电池中具有显着的倍率能力,并建议与全电池应用兼容。每个锂离子阵列的性能似乎与正极的不同结构,形态和电化学特征密切相关。因此,迄今为止,在大部分条件下在锂半电池中进行的MWCNTs阳极全电池研究是在各种条件下进行的。MWCNTs / Li [Ni 1/3 Co 1/3 Mn 1/3 ] O 2 结合显示出在循环稳定性,可逆容量和库仑效率方面的良好前景,这充分证明了MWCNTs作为锂离子电池阳极的潜在适用性。
更新日期:2018-01-11
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