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Recent topics on catalytic transformations of aromatic molecules via η6-arene transition metal complexes
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-01-12 , DOI: 10.1016/j.tetlet.2018.01.036
Shin Takemoto , Hiroyuki Matsuzaka

The π-complexation of an arene to a transition metal center delivers many useful reactivities to the arene moiety. Although synthetic methodologies that take advantage of such π-coordination have mostly been developed as stoichiometric processes, there have been considerable recent advances in the catalytic transformations of aromatic molecules through their activation in the form of transition metal η6-arene complexes. These advances include the π-coordination catalyzed transformations of aryl-heteroatom and side-chain CH and CC bonds and the palladium-catalyzed CH functionalization in pre-formed transition metal η6-arene complexes. This digest paper aims to provide a concise view of these recent advances in the area of transition metal η6-arene complexes.



中文翻译:

经由η上的芳族分子的催化转化最近的议题6 -arene过渡金属配合物

芳烃与过渡金属中心的π-络合为芳烃部分提供许多有用的反应性。虽然可充分利用这样的π-协调的合成方法大多已被开发为化学计量的过程中,也出现在过渡金属η的形式通过它们的活化是最近在芳族分子的催化转化相当大的进展6个-arene络合物。这些进展包括的芳基-杂原子和侧链C的π协调催化转化H和13 C C键和钯催化Ç在预先形成的过渡金属板H官能η 6个-arene络合物。本摘要旨在简要介绍过渡金属η领域中的这些最新进展。6-芳烃配合物。

更新日期:2018-01-12
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