Discotic mesogens P/n‐M (n=12, 16, 18, M=2 H, Zn and Cu) bearing a porphyrin core, triazole linkages and peripheral 3,4,5‐trialkoxybenzyl units have been synthesized by a click‐chemistry approach. The thermal behavior, photophysical properties and morphologies of these compounds were investigated by polarized optical microscopy (POM), differential scanning calorimetry (DSC), XRD, UV and PL, SEM and TEM. These compounds can self‐assemble into hexagonal columnar phases in their pure states and form organogels in 1,4‐dioxane with unusually flower‐like sphere morphology. The supramolecular complexes of P/18‐Zn with C₇₀ or 4,7‐di‐4‐pydriyl‐2,1,3‐benzothadiazole can display hexagonal columnar phases too. Additionally, zinc porphyrin compounds P/n‐Zn show binding selectivity to Cu²⁺ among a series of cations in THF/H₂O.

中文翻译：

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具有三唑键和外围烷基链的介孔取代卟啉介晶的合成和性质

通过点击化学合成了带有卟啉核，三唑键和外围3,4,5-三烷氧基苄基单元的盘状介晶P / n- M（n = 12、16、18 ，M = 2 H，Zn和Cu）方法。通过偏振光学显微镜（POM），差示扫描量热法（DSC），XRD，UV和PL，SEM和TEM研究了这些化合物的热行为，光物理性质和形态。这些化合物可以在其纯态下自组装成六方柱状相，并在1,4-二恶烷中形成具有异常花状球状形态的有机凝胶。P / 18-Zn与C ₇₀的超分子复合物或4,7-二-4-吡啶基-2,1,3-苯并噻二唑也可以显示六方柱状相。另外，锌卟啉化合物P / Ñ -Zn显示结合选择性的Cu ²⁺之间的THF / H一系列阳离子的₂ O.