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Hydrogenation of carbon dioxide under atmospheric pressure and low temperature
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2018-01-12 , DOI: 10.1016/j.ijhydene.2017.12.124
Yi Zhao , Xinfeng Qian , Xiaochu Zhao , Zili Zhang

In order to realize the effective reduction and utilization of carbon dioxide (CO2) in coal-fired flue gas, a process was developed under atmospheric pressure that uses KBH4 as an efficient hydrogen donor. By investigating the influencing factors of CO2 conversion, the optimal experimental conditions were determined and the average CO2 conversion efficiency of 50.36% was obtained when the KBH4 concentration was 0.2 mol/L, reaction temperature was 50 °C, solution pH was 8, and flow rate was 300 mL/min. The experimental results also verified that the coexisting gases such as sulfur dioxide (SO2), nitric oxide (NO) and oxygen (O2) in flue gas had no significant competition or inhibition effect on CO2 conversion. Meanwhile, the conversion products were analyzed by an Ion Chromatography (IC) and Fourier Transform Infrared Spectroscopy (FT-IR), and the results proved that the main reaction product was formate. Combined with the relevant literatures, the mechanism of CO2 reaction with KBH4 was proposed.



中文翻译:

在常压和低温下加氢二氧化碳

为了有效地减少和利用燃煤烟道气中的二氧化碳(CO 2),开发了一种在大气压下使用KBH 4作为有效氢供体的方法。通过研究CO 2转化的影响因素,确定了最佳实验条件,当KBH 4浓度为0.2 mol / L,反应温度为50°C,溶液pH为8时,平均CO 2转化效率为50.36%。,流速为300mL / min。实验结果还验证了二氧化硫(SO 2),一氧化氮(NO)和氧气(O 2烟气中的)对CO 2转化没有明显的竞争或抑制作用。同时,通过离子色谱(IC)和傅里叶变换红外光谱(FT-IR)分析了转化产物,结果证明主要反应产物为甲酸盐。结合相关文献,提出了CO 2与KBH 4反应的机理。

更新日期:2018-01-12
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