In article number 1702928, Indrajit Shown, Li‐Chyong Chen, Kuei‐Hsien Chen, and co‐workers report a black titania with dual active sites (Ni‐nanoclusters and oxygen vacancy) for photocatalytic carbon dioxide (CO₂) reduction via artificial photosynthesis with H₂O and simulated sunlight. The intentionally introduced dual active sites lead to not only high photocatalytic activity, but also to selective solar fuel production under simulated solar light. The CO₂ adsorption and activation capability of the catalyst is demonstrated using computational study and the underlying mechanism in charge transfer and product formation is highlighted.

中文翻译：

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人工光合作用：镍-纳米团簇修饰的黑色TiO2，具有双重活性位点，可选择性还原光催化二氧化碳（Small 2/2018）

在编号1702928中，Indrajit Shown，陈立清，陈奎贤和他的同事报告了一种具有双重活性位点（镍纳米簇和氧空位）的黑钛白粉，可通过人工光合作用还原光催化二氧化碳（CO ₂）。 H ₂ O和模拟阳光。故意引入的双重活性位点不仅导致高的光催化活性，而且导致在模拟太阳光下选择性生产太阳能燃料。通过计算研究证明了催化剂对CO _2的吸附和活化能力，并突出了电荷转移和产物形成的潜在机理。