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Iridium-Catalyzed Hydroarylation of Conjugated Dienes via π-Allyliridium Intermediates
Organic Letters ( IF 4.9 ) Pub Date : 2018-01-11 00:00:00 , DOI: 10.1021/acs.orglett.7b03969 Midori Nagamoto 1 , Hideki Yorimitsu 1 , Takahiro Nishimura 2
Organic Letters ( IF 4.9 ) Pub Date : 2018-01-11 00:00:00 , DOI: 10.1021/acs.orglett.7b03969 Midori Nagamoto 1 , Hideki Yorimitsu 1 , Takahiro Nishimura 2
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A hydroxoiridium/cod complex efficiently catalyzed hydroarylation of conjugated dienes with arenes bearing an acidic N–H bond as a directing group, which can form an amidoiridium species as an active intermediate for C–H activation. A π-allyliridium(III) complex was isolated as a key intermediate leading to the addition product.
中文翻译：
π-烯丙基铱中间体的共轭二烯的铱催化加氢芳基化
羟基铱/鳕鱼复合物可以有效地催化共轭二烯与带有酸性N–H键作为导向基团的芳烃的加氢芳基化反应，而芳烃可以形成酰胺铱，作为CH–H活化的活性中间体。分离出π-烯丙基铱（III）配合物作为导致加成产物的关键中间体。
更新日期：2018-01-11
中文翻译：
π-烯丙基铱中间体的共轭二烯的铱催化加氢芳基化
羟基铱/鳕鱼复合物可以有效地催化共轭二烯与带有酸性N–H键作为导向基团的芳烃的加氢芳基化反应，而芳烃可以形成酰胺铱，作为CH–H活化的活性中间体。分离出π-烯丙基铱（III）配合物作为导致加成产物的关键中间体。
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