Herein, we reported three polyzwitterions: binary one (PAAS) synthesized with acrylamide (AM) and 2-((3-methacrylamidopropyl)dimethylammonio)ethyl sulfite (MAPES), and two ternary (PABA, PADA) with AM, MAPES and benzene sulfonamides. The polyzwitterions were successful synthesized and proved by FT-IR and ¹H NMR. TGA analysis provided scientific result about thermal stability, and SEM images revealed bead model microstructure of self-assemblies which was composed of polyzwitterions and sodium lauryl sulfonate (SLS) of 0.5–3.0 g/L. Synergy of hydrogen bonding, hydrophobic association and electrostatic effect from self-assembly systems contributed to higher apparent viscosity (η), lower interfacial tension (IFT), electro-conductibility (σ) and greater peak height from ¹H NMR. Exploration for adsorption of SLS by molecular structure and interaction further explained low IFT and electro-conductibility of self-assembly system through D-value of C_ps and C[γ_s] as well as C_s and C[x]. Rheological property test including anti-shear, temperature tolerance, resistance to salt and viscoelasticity revealed that polyzwitterion-SLS 1.0 g/L was remarkable comparing with same series of self-assemblies. Moreover, PABA-SLS-1.0 g/L system demonstrated distinct temperature-responsive performance at 100 °C, 170 s⁻¹ and salt irritation behavior for Na⁺, Ca²⁺, Mg²⁺.

在此，我们报道了三种多性两性离子：与丙烯酰胺（AM）和2-（（3-甲基丙烯酰胺基丙基）二甲基铵）乙基亚硫酸盐（MAPES）合成的二元一（PAAS），以及与AM，MAPES和苯磺酰胺合成的二元（PABA，PADA）。 。聚两性离子已成功合成，并通过FT-IR和¹ H NMR证明。TGA分析提供了有关热稳定性的科学结果，并且SEM图像显示了由两性离子和0.5-3.0 g / L的十二烷基磺酸钠（SLS）组成的自组装珠模型微观结构。自组装系统的氢键，疏水缔合和静电效应的协同作用有助于提高表观粘度（η），降低界面张力（IFT），导电性（σ）和从^1开始的更大峰高1 H NMR。勘探由分子结构和相互作用的SLS吸附通过的d值进一步解释低IFT和自组装系统的电传导性Ç _PS和Ç [ γ_小号]以及Ç_小号和Ç [ X ]。流变性能测试（包括抗剪切性，耐温性，耐盐性和粘弹性）表明，与两套相同的自组装件相比，聚两性离子-SLS 1.0 g / L显着。此外，PABA-SLS-1.0 g / L系统在100°C，170 s ^-1时表现出独特的温度响应性能，并且对Na ⁺，Ca ^2+具有盐分刺激性，镁²⁺。