A well-defined unimolecular channel facilitates chloride transport,Chemical Communications

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A well-defined unimolecular channel facilitates chloride transport
Chemical Communications ( IF 4.3 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1039/c7cc09200h
Sujun Chen _{1,

2,

3,

4,

5} , Yongliang Zhao _{1,

2,

3,

4,

5} , Chunyan Bao _{1,

2,

3,

4,

5} , Yaowu Zhou _{1,

2,

3,

4,

5} , Chenxi Wang _{1,

2,

3,

4,

5} , Qiuning Lin _{1,

2,

3,

4,

5} , Linyong Zhu _{1,

2,

3,

4,

5}

Affiliation

A unimolecular ion channel was optimized by functionalization with a new type of rigid-rod oligomer. The macrocycle pendant endows chloride selectivity and the fluorescence feature and suitable length of the rod facilitates the visual insertion of channels into the lipid bilayer, resulting in efficient ion transport with an EC₅₀ value of 0.36 μM.

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