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Sintering behavior, phase evolutions and microwave dielectric properties of LaGaO3-SrTiO3 ceramics modified by CeO2 additives
Ceramics International ( IF 5.1 ) Pub Date : 2018-01-10
Zixing Wang, Changlai Yuan, Baohua Zhu, Qin Feng, Fei Liu, Jiwen Xu, Changrong Zhou, Guohua Chen

Crystal structures and microwave dielectric properties of (1-x) LaGaO3-x SrTiO3 (x=0.4, 0.5, 0.6) and 0.4SrTiO3−0.6LaGaO3-yCeO2 (y=0, 0.05, 0.1, 0.2) ceramics were investigated. As the x values increased, the orthorhombic changed to tetragonal perovskite structure at x=0.6 in LaGaO3-SrTiO3 system ceramics. However, numerous secondary phases were detected in LaGaO3-SrTiO3 system ceramics. Surprisingly, CeO2 additives could effectively suppress formation of secondary phases of 0.4SrTiO3−0.6LaGaO3 ceramics as Ce ions could be incorporated into host crystal lattices, leading to significantly improvement of optimal Q×f values from 35,354 GHz to 62,150 GHz. The Raman spectra exhibited that the modes associated with CeO2 phase became more obvious with increasing CeO2 additives. The 0.4SrTiO3−0.6LaGaO3−0.05CeO2 ceramics, sintered at 1475 °C/4 h, exhibited superior microwave dielectric properties with εr=32.9, Q×f =62,150 GHz and τf=−26.6 ppm/°C.



中文翻译:

CeO 2添加剂改性的LaGaO 3 -SrTiO 3陶瓷的烧结行为,相演化和微波介电性能

(1- x)LaGaO 3 - x SrTiO 3x = 0.4,0.5,0.6)和0.4SrTiO 3 -0.6LaGaO 3 - y CeO 2y = 0,0.05,0.1,0.2 )的晶体结构和微波介电性能陶瓷进行了调查。随着x值的增加,LaGaO 3 -SrTiO 3系陶瓷中的正交晶在x = 0.6时变为四方钙钛矿结构。但是,在LaGaO 3 - SrTiO 3系陶瓷中检测到许多次生相。令人惊讶的是,CeO2添加剂可以有效地抑制0.4SrTiO 3 -0.6LaGaO 3陶瓷第二相的形成,因为Ce离子可以掺入主体晶格中,从而导致最佳Q×f值从35,354 GHz显着提高到62,150 GHz。拉曼光谱显示,随着CeO 2添加剂的增加,与CeO 2相相关的模式变得更加明显。所述0.4SrTiO 3 -0.6LaGaO 3 -0.05CeO 2个陶瓷,在1475烧结℃/ 4小时,显示出优异的微波电介质特性与ε - [R = 32.9,Q×˚F = 62150 GHz和τ ˚F = -26.6 PPM /℃ 。

更新日期:2018-01-10
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