Metal-Free Electrocatalytic Aerobic Hydroxylation of Arylboronic Acids,Organic Letters

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Metal-Free Electrocatalytic Aerobic Hydroxylation of Arylboronic Acids
Organic Letters ( IF 4.9 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1021/acs.orglett.7b02483
Jian Luo ₁ , Bo Hu ₁ , Alyssa Sam ₁ , T. Leo Liu ₁

Affiliation

Hydroxylation of arylboronic acids to aryl alcohols was realized by a scalable electrocatalytic method. The present electrochemical hydroxylation employs low-cost methyl viologen as an organic cathodic electrocatalyst and involves O₂ as a green and sustainable reactant. The electrochemical kinetic studies shown here can be a powerful tool to gain rich mechanistic and kinetic information and thus an in-depth understanding of the electrocatalytic mechanism.

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