[Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2-Vinylcyclopropa[b]indolines from 2-Vinylindoles,Organic Letters

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[Copper(I)(Pyridine-Containing Ligand)] Catalyzed Regio- and Steroselective Synthesis of 2-Vinylcyclopropa[b]indolines from 2-Vinylindoles
Organic Letters ( IF 4.9 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1021/acs.orglett.7b03704
Valentina Pirovano ₁ , Elisa Brambilla ₁ , Giorgio Tseberlidis ₂

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A [copper(I)pyridine-containing ligand]-catalyzed reaction between 2-vinylindoles and diazo esters is described. The reaction allows for the synthesis of a series of 2-vinylcyclopropa[b]indolines with excellent levels of regio- and sterocontrol under mild conditions.

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