Amplification effect of circularly polarized luminescence induced from binaphthyl-based zinc(ii) chiral coordination polymers†,Materials Chemistry Frontiers

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Amplification effect of circularly polarized luminescence induced from binaphthyl-based zinc(ii) chiral coordination polymers†
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2018-01-10 00:00:00 , DOI: 10.1039/c7qm00560a
Yuxiang Wang _{1,

2,

3,

4,

5} , Xiaojing Li _{1,

2,

3,

4,

5} , Lan Yang _{1,

2,

3,

4,

5} , Wei-Yin Sun _{2,

3,

4,

5,

6} , Chengjian Zhu _{2,

3,

4,

5,

6} , Yixiang Cheng _{1,

2,

3,

4,

5}

Affiliation

Two novel binaphthyl-based dipyrrin zinc(II) chiral coordination polymers (R/S-P1) can be synthesized by coordination reaction. R/S-P1 can exhibit stronger Cotton effects and circularly polarized luminescence (CPL) emission signals compared with the chiral complex monomers (R/S-M1). The luminescence dissymmetry factors (g_lum) can reach as high as 9 × 10⁻³ for R/S-P1.

中文翻译：

联萘基锌（ii）手性配位聚合物诱导的圆偏振发光的放大作用†

通过配位反应可以合成两种新型的基于联萘基的双吡啶锌（II）手性配位聚合物（R / S -P1 ）。与手性配合物单体（R / S- M1）相比，R / S- P1可以表现出更强的棉花效应和圆偏振发光（CPL）发射信号。对于R / S -P1 ，发光不对称因子（g _lum）可高达9×10 ^-3。

更新日期：2018-01-10

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