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Maximizing the production of hydrogen and carbon nanotubes: Effect of Ni and reaction temperature
International Journal of Hydrogen Energy ( IF 8.1 ) Pub Date : 2018-01-10 , DOI: 10.1016/j.ijhydene.2017.12.131
Syedvali Pinjari , Madan Kumar Kumaravelan , Venkat Chalapathirao Peddy , Sriganesh Gandham , Jagannadharao Patruni , Sridevi Velluru , Pramod Kumar

With the objective of maximizing hydrogen and CNTs production, the catalytic cracking of naphtha has been carried out at progressive reaction temperatures i.e. from 600 to 750 °C. The ZSM-5 and nickel impregnated ZSM-5 were used as catalysts for cracking purpose in fluidization mode. The catalyst analysis imparted that impregnation of metallic nickel induces a strong adhesion on MFI structure of ZSM-5 associated with an enhancement in textural properties and acid density. In addition, the results disclose that the incorporation of nickel on ZSM-5 leads to increment in stability of catalyst which in turn pushes the yields of H2, CNTs and conversion to greater values of 3.29%, 4.84% and 90%, respectively. The as-grown carbon structures over the catalyst surface were found to be multiwall carbon nanotubes confirmed by Raman spectra and TGA analysis where they exhibited high quality (ID/IG = 0.65) and purity, respectively, at 750 °C.



中文翻译:

最大化氢和碳纳米管的生产:镍和反应温度的影响

为了最大化氢气和CNT的生产,石脑油的催化裂化已在渐进的反应温度(即600至750°C)下进行。ZSM-5和镍浸渍的ZSM-5在流化模式下用作裂解目的的催化剂。催化剂分析表明,金属镍的浸渍在ZSM-5的MFI结构上引起了强烈的附着力,这与质地性能和酸密度的提高有关。另外,结果公开了在ZSM-5上引入镍导致催化剂稳定性的增加,这反过来又推动了H 2的产率。,CNT和转化为更高的值,分别为3.29%,4.84%和90%。发现在催化剂表面上生长的碳结构是通过拉曼光谱和TGA分析证实的多壁碳纳米管,它们 在750℃下分别表现出高质量(ID / IG = 0.65)和纯度。

更新日期:2018-01-10
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