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Diaminomaleonitrile based chromo-fluorescent receptor molecule for selective sensing of Mn(II) and Zn(II) ions
Sensors and Actuators B: Chemical ( IF 8.4 ) Pub Date : 2018-01-10 , DOI: 10.1016/j.snb.2018.01.106
Suman Swami , Arunava Agarwala , Debasis Behera , Rahul Shrivastava

A new class of chemosensors (L1-L3) based on sequential coupling of 2,3-diaminomaleonitrile, 4-formyl-1-substituted phenyl-pyrazole-3-carboxylate and 2-hydroxy-1-naphthaldehyde through imine linkages were successfully designed and synthesized. The synthesized chemosensors showed quick colorimetric response with excellent selectivity and sensitivity towards detection of Mn2+ and Zn2+ ions in preference of other cations. Along with this, chemosensors also serve as fluorescent turn ‘off’ and turn ‘on’ switch for detection of Mn2+ and Zn2+ ion respectively. Analytical characterization were evaluated using UV–vis titration, fluorescent titration and Job’s plot methods which revealed that sensor interact with Mn2+ and Zn2+ ion in 1:1 and 1:2 binding stoichiometry respectively.



中文翻译:

基于二氨基马腈的发色荧光受体分子,可选择性地感测Mn(II)和Zn(II)离子

基于亚胺键,成功地设计了基于2,3-二氨基马腈,4-甲酰基-1-取代的苯基-吡唑-3-羧酸酯和2-羟基-1-萘醛的顺序偶联的新型化学传感器(L1-L3),并合成的。合成的化学传感器显示出快速的比色响应,对锰2+和锌2+离子的检测具有极好的选择性和灵敏度,优于其他阳离子。除此之外,化学传感器还用作荧光灯的“关闭”和“开启”开关,分别用于检测Mn 2+和Zn 2+离子。使用UV-vis滴定法,荧光滴定法和Job's plot方法评估了分析表征,结果表明传感器与Mn 2+相互作用和Zn 2+离子分别以1:1和1:2的化学计量比结合。

更新日期:2018-01-10
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