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The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2018-01-17 , DOI: 10.1021/jacs.7b09446
Zachary X Giustra 1 , Shih-Yuan Liu 1
Affiliation  

Boron-nitrogen heteroarenes hold great promise for practical application in many areas of chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation with respect to these compounds' synthesis. This Perspective discusses in detail the most recent advances in methods pertaining to the preparation of BN-isosteres of benzene, naphthalene, and their derivatives. Additional focus is placed on the progress enabled by these syntheses toward functional utility of such BN-heterocycles in biochemistry and pharmacology, materials science, and transition-metal-based catalysis. The prospects for future research efforts in these and related fields are also assessed.

中文翻译:


氮硼烷化学的最新进展:新的合成方法和应用



硼氮杂芳烃在许多化学领域的实际应用中具有广阔的前景。对实现这一潜力的持久兴趣反过来又推动了这些化合物合成方面的长期创新。本综述详细讨论了苯、萘及其衍生物的 BN 电子等排物制备方法的最新进展。另外的重点是这些合成在生物化学和药理学、材料科学和过渡金属催化方面的功能实用性方面所取得的进展。还评估了这些及相关领域未来研究工作的前景。
更新日期:2018-01-17
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