The inorganic–organic hybrid nanoparticles Gd₄³⁺[AlPCS₄]₃⁴⁻ and La₄³⁺[TPPS₄]₃⁴⁻ ([AlPCS₄]⁴⁻: aluminium(III) chlorido phthalocyanine tetrasulfonate; [TPPS₄]⁴⁻: tetraphenylporphine sulfonate) are shown for the first time. Both were obtained via aqueous synthesis and contain extremely high contents of [AlPCS₄]₃⁴⁻ (81 wt%) and [TPPS₄]₃⁴⁻ (83 wt%). They show efficient singlet oxygen (¹O₂) production upon daylight and red-light irradiation. Photocatalysis is evidenced via dye degradation as a proof-of-the-concept and proceeds with daylight and even red-light illumination.

中文翻译：

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含酞菁和四苯基卟啉阴离子的盐杂化纳米颗粒显示出有效的单线态氧产生和光催化作用

无机-有机杂化纳米粒子Gd ₄ ³⁺ [AlPCS ₄ ] ₃ ^4-和La ₄ ³⁺ [TPPS ₄ ] ₃ ^4-（[AlPCS ₄ ] ^4-：铝（III）氯酞菁四磺酸铝； [TPPS ₄ ] ^{4 -}：首次显示四苯基卟啉磺酸盐。既获得经由含水合成和含有[AlPCS的极高含量₄ ] ₃ ^4- （81重量％）和[TPPS ₄ ] ₃ ^4-（83重量％）。它们在日光和红光照射下显示出有效的单线态氧（¹ O ₂）产生。通过染料降解可以证明光催化作用是一种概念验证，并随着日光甚至红光的照射而继续进行。