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Cluster Formation in the Superconducting Complex Intermetallic Compound Be21Pt5
Accounts of Chemical Research ( IF 18.3 ) Pub Date : 2018-01-09 00:00:00 , DOI: 10.1021/acs.accounts.7b00561
Alfred Amon 1 , Alim Ormeci 1 , Matej Bobnar 1 , Lev G. Akselrud 1, 2 , Maxim Avdeev 3 , Roman Gumeniuk 4 , Ulrich Burkhardt 1 , Yurii Prots 1 , Christoph Hennig 5 , Andreas Leithe-Jasper 1 , Yuri Grin 1
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Materials with the crystal structure of γ-brass type (Cu5Zn8 type) are typical representatives of intermetallic compounds. From the electronic point of view, they are often interpreted using the valence electron concentration approach of Hume–Rothery, developed previously for transition metals. The γ-brass-type phases of the main-group elements are rather rare. The intermetallic compound Be21Pt5, a new member of this family, was synthesized, and its crystal structure, chemical bonding, and physical properties were characterized.

中文翻译:

超导复合金属间化合物Be 21 Pt 5中的团簇形成

具有γ-黄铜型(Cu 5 Zn 8型)晶体结构的材料是金属间化合物的典型代表。从电子的角度来看,它们通常使用休ume-拉特里(Hume-Rothery)的价电子浓度法(以前为过渡金属开发)来解释。主族元素的γ-黄铜型相非常罕见。合成了该族的新成员金属间化合物Be 21 Pt 5,并对其晶体结构,化学键和物理性质进行了表征。
更新日期:2018-01-09
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