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A facile method for the preparation of carbodiimides from thioureas and (Boc)2O
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2018-01-09 , DOI: 10.1016/j.tetlet.2018.01.025
He Wu , Yan-Fang Sun , Chen Zhang , Chun-Bao Miao , Hai-Tao Yang

A concise method for the preparation of carbodiimides from thioureas using di-tert-butyl dicarbonate [(Boc)2O] as the dehydrosulfurizative reagent has been developed. Using DMAP as the catalyst, a variety of symmetric and asymmetric 1,3-diaryl thioureas were converted into the corresponding carbodiimides efficiently in a short time.



中文翻译:

一种从硫脲和(Boc)2 O制备碳二亚胺的简便方法

使用用于从硫脲制备碳化二亚胺的简明方法二-丁基二碳酸酯[(BOC)2 O]作为dehydrosulfurizative试剂已经研制成功。使用DMAP作为催化剂,可以在短时间内将各种对称和不对称的1,3-二芳基硫脲有效地转化为相应的碳二亚胺。

更新日期:2018-01-09
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