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Sodium ferric EDTA-derived Fe-N-C material for selectively electrocatalytic synthesis of hydrogen peroxide
Materials Letters ( IF 3 ) Pub Date : 2018-01-09
Xiang-Hui Yan, Ziwei Meng, Jia Liu, Tong Xue

A cheap sodium ferric EDTA-derived material (EDTAFeNa-KB-HT1) was prepared via one-step pyrolysis of a complex of Ketjenblack EC-300J and inorganic-organic hybrid EDTAFeNa, which was employed as both nitrogen and ferric precursors. The EDTAFeNa-KB-HT1 was proved to be an iron and nitrogen co-doped Fe-N-C material with micro-mesoporous structure and large surface area. The EDTAFeNa-KB-HT1 exhibited high selectivity (80∼100%) towards oxygen reduction reaction for electrocatalytic synthesis of hydrogen peroxide (H2O2) concurrently with generation of large current density, which could be potentially a safe, efficient and environment-friendly fuel cell method for the scale production of H2O2.



中文翻译:

EDTA衍生的铁三氧化二铁钠材料,用于选择性电催化合成过氧化氢

通过Ketjenblack EC-300J与无机-有机杂化EDTAFeNa的复合物的一步热解制备了廉价的EDTA钠铁金属材料(EDTAFeNa-KB-HT1),该复合物同时用作氮和铁的前体。EDTAFeNa-KB-HT1被证明是一种铁和氮共掺杂的Fe-NC材料,具有微中孔结构和大表面积。EDTAFeNa-KB-HT1对氧还原反应具有很高的选择性(80%至100%),用于电催化合成过氧化氢(H 2 O 2),并产生大电流密度,这可能是安全,高效且环境友好的。 H 2 O 2规模化生产的友好燃料电池法。

更新日期:2018-01-09
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