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Pd‐Catalyzed C‐H/N‐H Arylation: One‐Pot Synthesis of Indolo[1, 2‐f]phenanthridines
ChemistrySelect ( IF 2.1 ) Pub Date : 2018-01-09 , DOI: 10.1002/slct.201701939
Lingkai Kong 1 , Qiyi Yao 1 , Mengdan Wang 1 , Ruizhuo Sun 1 , Yanzhong Li 1
Affiliation  

A novel Pd‐catalyzed method for the synthesis of indolo[1, 2‐f]phenanthridines from 2‐bromo‐2′‐iodo‐1,1′‐biphenyl and indole derivatives has been reported. The reaction involves direct N−H and C2‐H arylation of indole. This Pd‐catalyzed double arylation provides a useful route to synthesize indolo[1, 2‐f]phenanthridine derivatives from simple and readily accessible starting materials.

中文翻译:

Pd催化的C-H / N-H芳基化:吲哚[1,2-f]菲啶的一锅合成

报道了一种新型的钯催化的方法,该方法由2-溴-2'-碘-1,1'-联苯和吲哚衍生物合成吲哚[ 1,2- f ]菲啶。该反应涉及吲哚的直接NH和C2-H芳基化。这种Pd催化的双芳基化为从简单易得的起始原料合成吲哚并[1,2- f ]菲啶衍生物提供了一条有用的途径。
更新日期:2018-01-09
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