Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-01-08 , DOI: 10.1002/anie.201713194 Juan-Ding Xiao 1 , Lili Han 2 , Jun Luo 2 , Shu-Hong Yu 1 , Hai-Long Jiang 1
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Based on a semiconductor-like metal–organic framework (MOF), the Pt@MOF/Au catalyst integrates the surface plasmon resonance excitation of Au nanorods with a Pt-MOF Schottky junction, which extends the light absorption of the MOF from the UV to the visible region and greatly accelerates charge transfer. H.-L. Jiang et al. show in their Communication on page 1103 ff. that the spatial separation of Pt and Au particles by the MOF further steers the formation of charge flow and expedites electron migration, leading to a very high photocatalytic H2 production rate.
中文翻译：
封底：将等离子效应和肖特基结集成到金属-有机骨架复合材料中：引导电荷流以增强可见光光催化作用（Angew。Chem。Int。Ed。4/2018）
Pt @ MOF / Au催化剂基于类似半导体的金属-有机骨架（MOF），将Au纳米棒的表面等离振子共振激发与Pt-MOF肖特基结结合在一起，从而将MOF的光吸收范围从UV扩展到UV可见区域并大大加快了电荷转移。高 江等。请参见第1103页ff的“交流”中的内容。MOF对Pt和Au颗粒的空间分离进一步控制了电荷流的形成并加快了电子迁移，从而导致很高的光催化H 2生成速率。
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