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Measurements of Saturation Pressures for Trifluoroethene (R1123) and 3,3,3-Trifluoropropene (R1243zf)
Journal of Chemical & Engineering Data ( IF 2.6 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1021/acs.jced.7b00818
Yukihiro Higashi 1 , Naoya Sakoda 1, 2 , Md. Amirul Islam 1, 3 , Yasuyuki Takata 1, 2 , Shigeru Koyama 1, 4 , Ryo Akasaka 1, 5
Affiliation  

Saturation pressures for new low global warming potential refrigerants trifluoroethene (R1123, CF2═CHF) and 3,3,3-trifluoropropene (R1243zf, CF3CH═CH2) were measured by the isochoric method for temperatures between 278 and 377 K. Temperature was measured with a 25 Ω standard platinum resistance thermometer on ITS-90. Pressure was measured with a digital quartz pressure transducer. The experimental uncertainties in temperature and pressure are estimated to be 5 mK and 1 kPa (k = 2), respectively. New saturation-pressure correlations for the refrigerants have been formulated based on the present saturation-pressure data. The critical pressures of R1123 and R1243zf were also determined.

中文翻译:

三氟乙烯(R1123)和3,3,3-三氟丙烯(R1243zf)的饱和压力的测量

对于新的低全球变暖潜能的制冷剂三氟乙烯饱和压力(R1123,CF 2 ═CHF)和3,3,3-三氟丙烯(R1243zf,CF 3 CH = CH 2)用等容的方法测定为278和377 K之间的温度下用ITS-90上的25Ω标准铂电阻温度计测量温度。用数字石英压力传感器测量压力。温度和压力的实验不确定性分别估计为5 mK和1 kPa(k = 2)。基于当前的饱和压力数据,已经制定了用于制冷剂的新的饱和压力相关性。还确定了R1123和R1243zf的临界压力。
更新日期:2018-01-08
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