Synthesis of zeolitic tetrazolate-imidazolate frameworks (ZTIFs) in ethylene glycol†,Inorganic Chemistry Frontiers

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Synthesis of zeolitic tetrazolate-imidazolate frameworks (ZTIFs) in ethylene glycol†
Inorganic Chemistry Frontiers ( IF 6.1 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1039/c7qi00765e
Min-Yu Li _{1,

2,

3,

4,

5} , Hai-Xia Zhang _{1,

2,

3,

4,

5} , Fei Wang _{1,

2,

3,

4,

5} , Jian Zhang _{1,

2,

3,

4,

5}

Affiliation

Ethylene glycol (EG) as a universal solvent is used to reproducibly synthesize zeolitic tetrazolate imidazolate frameworks (ZTIF-11 to -13) in high yields. The phase-pure frl-type ZTIF-11 is confirmed to be permanently porous and shows high chemical stability as well as remarkable performance in the selective separation of CO₂ at ambient temperature.

中文翻译：

在乙二醇中合成沸石四唑酸酯-咪唑酸酯骨架（ZTIFs）†

乙二醇（EG）作为通用溶剂用于可再生地高产率合成沸石四唑盐咪唑酸盐骨架（ZTIF-11至-13）。证实纯相frl型ZTIF-11具有永久性的多孔性，并在环境温度下选择性分离CO ₂时显示出高化学稳定性以及出色的性能。

更新日期：2018-01-08

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