A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes,Green Chemistry

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A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes
Green Chemistry ( IF 9.3 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1039/c7gc03745g
Yunfei Tian _{1,

2,

3,

4} , Changqing Sun _{1,

2,

3,

4} , Ren Xiang Tan _{4,

5,

6,

7,

8} , Zhong-Quan Liu _{1,

2,

3,

4,

5}

Affiliation

A KI-mediated radical anti-Markovnikov addition of simple ketones and esters to unactivated alkenes was developed. Through this strategy, a wide range of complex carbonyl compounds can be conveniently synthesized in high selectivities. In addition, this method features high atom-economy and is transition-metal free, operationally simple and environmentally benign.

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