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A KI-mediated radical anti-Markovnikov addition of simple ketones/esters to unactivated alkenes
Green Chemistry ( IF 9.3 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1039/c7gc03745g
Yunfei Tian 1, 2, 3, 4 , Changqing Sun 1, 2, 3, 4 , Ren Xiang Tan 4, 5, 6, 7, 8 , Zhong-Quan Liu 1, 2, 3, 4, 5
Affiliation  

A KI-mediated radical anti-Markovnikov addition of simple ketones and esters to unactivated alkenes was developed. Through this strategy, a wide range of complex carbonyl compounds can be conveniently synthesized in high selectivities. In addition, this method features high atom-economy and is transition-metal free, operationally simple and environmentally benign.

中文翻译:

KI介导的将简单的酮/酯与未活化的烯烃加成的反马尔科夫尼科夫自由基

开发了KI介导的将简单的酮和酯添加到未活化的烯烃上的自由基抗马尔科夫尼科夫化合物。通过这种策略,可以方便地以高选择性合成各种复杂的羰基化合物。此外,该方法具有高原子经济性,无过渡金属,操作简单且对环境无害的特点。
更新日期:2018-02-06
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