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CuWO4 as a photocatalyst for room temperature aerobic benzylamine oxidation
Chemical Communications ( IF 4.3 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1039/c7cc07611h
Aaron D. Proctor 1, 2, 3, 4 , Shobhana Panuganti 1, 2, 3, 4 , Bart M. Bartlett 1, 2, 3, 4
Affiliation  

The aerobic photochemical oxidation of benzylamine was carried out on the ternary oxides CuWO4 and BiVO4 as a test proton-coupled-electron-transfer reaction in acetonitrile. Both oxides give the coupled imine product, N-benzylidenebenzylamine, in near quantitative (98–99%) yield, with rate constants of 0.34 h−1 g−1 and 0.70 h−1 g−1 for CuWO4 and BiVO4, respectively.

中文翻译:

CuWO 4作为室温好氧苄胺氧化的光催化剂

在三元氧化物CuWO 4和BiVO 4上进行苄胺的需氧光化学氧化,作为乙腈中质子偶合电子转移反应的测试。两种氧化物得到耦合亚胺产物,Ñ -benzylidenebenzylamine,接近定量(98-99%)的产量,具有0.34ħ速率常数-1-1和0.70ħ -1-1对钨酸铜4和BiVO 4分别。
更新日期:2018-01-25
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