CuWO4 as a photocatalyst for room temperature aerobic benzylamine oxidation,Chemical Communications

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CuWO4 as a photocatalyst for room temperature aerobic benzylamine oxidation
Chemical Communications ( IF 4.3 ) Pub Date : 2018-01-08 00:00:00 , DOI: 10.1039/c7cc07611h
Aaron D. Proctor _{1,

2,

3,

4} , Shobhana Panuganti _{1,

2,

3,

4} , Bart M. Bartlett _{1,

2,

3,

4}

Affiliation

The aerobic photochemical oxidation of benzylamine was carried out on the ternary oxides CuWO₄ and BiVO₄ as a test proton-coupled-electron-transfer reaction in acetonitrile. Both oxides give the coupled imine product, N-benzylidenebenzylamine, in near quantitative (98–99%) yield, with rate constants of 0.34 h⁻¹ g⁻¹ and 0.70 h⁻¹ g⁻¹ for CuWO₄ and BiVO₄, respectively.

中文翻译：

CuWO ₄作为室温好氧苄胺氧化的光催化剂

在三元氧化物CuWO ₄和BiVO ₄上进行苄胺的需氧光化学氧化，作为乙腈中质子偶合电子转移反应的测试。两种氧化物得到耦合亚胺产物，Ñ -benzylidenebenzylamine，接近定量（98-99％）的产量，具有0.34ħ速率常数^-1克^-1和0.70ħ ^-1克^-1对钨酸铜₄和BiVO ₄分别。

更新日期：2018-01-25

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