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Electrochemical C−H/N−H Activation by Water‐Tolerant Cobalt Catalysis at Room Temperature
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2018-01-17 , DOI: 10.1002/anie.201712647
Cong Tian 1 , Leonardo Massignan 1 , Tjark H. Meyer 1 , Lutz Ackermann 1
Affiliation  

Electrochemistry enabled C−H/N−H functionalizations at room temperature by external oxidant‐free cobalt catalysis. Thus, the sustainable cobalt electrocatalysis manifold proceeds with excellent levels of chemoselectivity and positional selectivity, and with ample scope, thus allowing electrochemical C−H activation under exceedingly mild reaction conditions at room temperature in water.

中文翻译:

室温下耐水钴催化电化学活化H / N-H

电化学在室温下通过外部无氧化剂钴催化实现了CH / NH功能化。因此,可持续的钴电催化歧管以优异的化学选择性和位置选择性,并且具有足够的作用范围进行,因此可以在室温下非常温和的反应条件下,在水中进行电化学CH活化。
更新日期:2018-01-17
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