Co(iii)-Catalyzed N-chloroamide-directed C–H activation for 3,4-dihydroisoquinolone synthesis†,Organic Chemistry Frontiers

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Co(iii)-Catalyzed N-chloroamide-directed C–H activation for 3,4-dihydroisoquinolone synthesis†
Organic Chemistry Frontiers ( IF 4.6 ) Pub Date : 2018-01-05 00:00:00 , DOI: 10.1039/c7qo01124e
Xiaolong Yu _{1,

2,

3,

4,

5} , Kehao Chen _{1,

2,

3,

4,

5} , Qi Wang _{1,

2,

3,

4,

5} , Wenjing Zhang _{1,

2,

3,

4,

5} , Jin Zhu _{1,

2,

3,

4,

5}

Affiliation

The synthesis of 3,4-dihydroisoquinolone via Co(III)-catalyzed C–H activation has been achieved for the first time. N-Chloroamides as a C–H activation directing synthon react effectively with alkenes at room temperature, enabling the incorporation of diverse reactive functionalities and substitution patterns into the target heterocycles.

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