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Protonated carbon nitride induced hierarchically ordered Fe2O3/HC3N4/rGO architecture with enhanced electrochemical sensing of nitrite
Sensors and Actuators B: Chemical ( IF 8.4 ) Pub Date : 2018-01-04 , DOI: 10.1016/j.snb.2018.01.073
Shuang Wang , Maoxiang Liu , Shanshan He , Shupeng Zhang , Xuchu Lv , Haiou Song , Jun Han , Duozhe Chen

A novel electrochemical nitrite (NaNO2) sensor is fabricated by combining Fe2O3 with protonated carbon nitride (HC3N4) and reduced graphene oxide (rGO). The smaller HC3N4 is distributed uniformly on the surface of the rGO support and acts as a nucleation site for the growth of Fe2O3. Conductive HC3N4 is a nano-bridge to connect and uniformly distribute Fe2O3, a catalytic center, to the support rGO to enhance the electrocatalytic performance. The Fe2O3/HC3N4/rGO electrode possesses high sensitivity of 0.04874 μA μM−1, wide linear response range spanning 25 nM to 3000 μM, a low detection limit of 18.55 nM (S/N = 3) and shows high selectivity for nitrite in the presence of common organic and inorganic interfering species (like NaCl, MgSO4, KNO3, ZnSO4, CaCl2, glucose, urea), fulfilling requirements for a nitrite sensor used in commercial applications.



中文翻译:

质子化的氮化碳诱导的Fe 2 O 3 / H C 3 N 4 / rGO体系分层结构,并增强了亚硝酸盐的电化学感应

通过将Fe 2 O 3与质子化的氮化碳(H C 3 N 4)和还原的氧化石墨烯(rGO)结合,制得了新型的电化学亚硝酸盐(NaNO 2)传感器。较小的H C 3 N 4均匀分布在rGO载体的表面上,并充当Fe 2 O 3生长的成核位点。导电性H C 3 N 4是一个纳米桥,用于连接并均匀分布催化中心Fe 2 O 3到载体rGO上,以增强电催化性能。铁2O 3 / H C 3 N 4 / rGO电极灵敏度高,为0.04874μAμM -1,线性响应范围宽,范围为25 nM至3000μM,检测限低,为18.55 nM(S / N = 3),显示出高选择性在常见的有机和无机干扰物质(如NaCl,MgSO 4,KNO 3,ZnSO 4,CaCl 2,葡萄糖,尿素)存在下,亚硝酸盐满足工业应用中亚硝酸盐传感器的要求。

更新日期:2018-01-04
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