Separation and Purification Technology ( IF 8.1 ) Pub Date : 2018-01-04 , DOI: 10.1016/j.seppur.2018.01.010 Mahmoud Nasrollahzadeh , Zahra Issaabadi , S. Mohammad Sajadi
During this paper, palladium nanoparticles were immobilized on the surface of Fe3O4 using Hibiscus tiliaceus L. extract as a stabilizing and reducing agent. The green synthesized Pd/Fe3O4 nanocomposite was characterized by FT-IR, UV–Vis, TEM, XRD, VSM, FESEM and EDS. The prepared Pd/Fe3O4 nanocomposite was used an efficient catalyst for the reduction of Cr(VI), 4-nitrophenol (4-NP) and 2,4-dinitrophenylhydrazine (2,4-DNPH). The catalytic activities of the Pd/Fe3O4 nanocomposite in reactions were monitored by using UV–Vis spectroscopy. It can be recovered and reused six times without remarkable loss of its catalytic activity.
中文翻译:
芙蓉提取物绿色合成Pd / Fe 3 O 4纳米复合材料及其在Cr(VI)和硝基化合物还原催化中的应用
在本文中,使用芙蓉提取物作为稳定剂和还原剂将钯纳米颗粒固定在Fe 3 O 4的表面上。通过FT-IR,UV-Vis,TEM,XRD,VSM,FESEM和EDS对绿色合成的Pd / Fe 3 O 4纳米复合材料进行了表征。制备的Pd / Fe 3 O 4纳米复合材料可用于还原Cr(VI),4-硝基苯酚(4-NP)和2,4-二硝基苯肼(2,4-DNPH)。Pd / Fe 3 O 4的催化活性反应中的纳米复合物通过使用UV-Vis光谱仪进行监测。它可以回收并重复使用六次,而不会显着降低其催化活性。