Homochiral hexanuclear nickel(ii) metallocyclic structures with high activity for the photocatalytic degradation of organic dyes†,Dalton Transactions

当前位置： X-MOL 学术 › Dalton Trans. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Homochiral hexanuclear nickel(ii) metallocyclic structures with high activity for the photocatalytic degradation of organic dyes†
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-01-04 00:00:00 , DOI: 10.1039/c7dt04436d
Abaid Ullah Malik _{1,

2,

3,

4} , Xia-li Zhou _{1,

2,

3,

4} , Sheng-nan Kong _{1,

2,

3,

4} , Ling-ling Li _{2,

3,

4,

5} , Xiao-li Bao _{2,

3,

4,

5} , Mou-hai Shu _{1,

2,

3,

4}

Affiliation

Enantiopure ligands, namely (R,R)- and (S,S)-2,2′-(1,4-phenylene) bis(4,5-dihydrothiazole-4-carboxylic acid) (H₂L^RR, and H₂L^SS) were synthesized, and homochiral metallocyclic rings {Ni₆L^RR₆(H₂O)₁₂} (1^RR) and {Ni₆L^SS₆(H₂O)₁₂} (1^SS) were obtained and their structures were determined. The complexes exhibit excellent activity for the photocatalytic degradation of organic dyes.

中文翻译：

具有高活性的手性六核镍（ii）金属环结构对有机染料的光催化降解作用†

对映体纯配体，即（R，R）-和（S，S）-2,2'-（1,4-亚苯基）双（4,5-二氢噻唑-4-羧酸）（H ₂ L ^RR和H合成了₂ L ^SS），并形成了同手性金属环{Ni ₆ L ^RR₆（H ₂ O）₁₂ }（1 ^RR）和{Ni ₆ L ^SS₆（H ₂ O）₁₂ }（1 ^SS）并确定其结构。该络合物对有机染料的光催化降解表现出优异的活性。

更新日期：2018-01-04

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11