As a rigid and planar aza-based heteroaromatic scaffold, hexaazatriphenylene (HAT) exhibits excellent electron-deficient property and high π-π stacking tendency, which makes it an ideal building block in the construction of supramolecular architectures and functional materials. In addition, HATs have also been picked out as building blocks for the construction of novel porous organic polymers, one of the most attractive fields of porous materials in the past decade, which includes intrinsic microporosity (PIMs), π-conjugated microporous polymers (CMPs), and covalent organic frameworks (COFs). In this digest paper, the synthetic methods of HAT derivatives have been briefly introduced and some recent advances of HATs in the applications of supramolecular self-assembly and porous organic materials have been highlighted.

作为刚性且平面的氮杂杂芳族骨架材料，六氮杂苯并菲（HAT）表现出出色的电子缺陷性质和高π-π堆积趋势，这使其成为超分子结构和功能材料构造的理想构建基块。此外，HATs还被选作构建新型多孔有机聚合物的基石，这是过去十年中多孔材料最吸引人的领域之一，其中包括固有微孔率（PIM），π共轭微孔聚合物（CMP） ）以及共价有机框架（COF）。在本摘要文件中，简要介绍了HAT衍生物的合成方法，并重点介绍了HAT在超分子自组装和多孔有机材料中的应用方面的一些最新进展。