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Construction of rGO wrapping octahedral Ag-Cu2O heterostructure for enhanced visible light photocatalytic activity
Applied Catalysis B: Environment and Energy ( IF 22.1 ) Pub Date : 2018-01-04 , DOI: 10.1016/j.apcatb.2018.01.003
Qi Wei , Yang Wang , Haiying Qin , Jinming Wu , Yangfang Lu , Hongzhong Chi , Fan Yang , Bin Zhou , Houlin Yu , Jiabin Liu

A ternary reduced graphene oxide wrapped octahedral Ag-Cu2O (Ag-Cu2O/rGO) photocatalyst has been synthesized through a facile one-pot water bath method at 55 °C. The ternary Ag-Cu2O/rGO composites possessed a novel heterostructure, in which Cu2O octahedra were decorated with dense Ag nanoparticles and were wrapped with thin rGO nanosheets. The ternary Ag-Cu2O/rGO photocatalyst exhibited much higher activity in photodegradations of phenol in water under visible light than either pure Cu2O or binary Cu2O/rGO or Ag-Cu2O composites. The photo-excited electrons from Cu2O transferred to rGO and Ag, leading to the separation of the electron-hole pairs. The incorporation of rGO not only suppressed the recombination of electron-hole pairs but also prevented the agglomeration of Ag nanoparticles. Ag nanoparticles played an important role in the photocatalysis owing to the surface plasmon resonance.



中文翻译:

rGO包裹八面体Ag-Cu 2 O异质结构以增强可见光光催化活性的构建

通过简便的一锅水浴法在55°C下合成了三元还原石墨烯包裹的八面体Ag-Cu 2 O(Ag-Cu 2 O / rGO)光催化剂。三元Ag-Cu 2 O / rGO复合材料具有新颖的异质结构,其中Cu 2 O八面体用致密的Ag纳米颗粒装饰,并包裹有薄的rGO纳米片。与纯Cu 2 O或二元Cu 2 O / rGO或Ag-Cu 2 O复合材料相比,三元Ag-Cu 2 O / rGO光催化剂在可见光下对水中苯酚的光降解具有更高的活性。来自Cu 2的光激发电子O转移到rGO和Ag,导致电子-空穴对的分离。rGO的引入不仅抑制了电子-空穴对的重组,而且还防止了Ag纳米粒子的团聚。由于表面等离子体共振,Ag纳米颗粒在光催化中起重要作用。

更新日期:2018-01-04
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