当前位置: X-MOL 学术Adv. Synth. Catal. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Synthesis of 7‐Azaindole Amidated Derivatives: An Efficient Usage of Acyl Azides as the Nitrogen Source
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2018-01-16 , DOI: 10.1002/adsc.201701336
Wei-Huan Li 1 , Lin Dong 1
Affiliation  

The dual behaviour of acyl azides in transition‐metal‐catalyzed direct C−H amidation is investigated. Variously substituted acyl azides reacted smoothly with 7‐azaindoles providing a diversity of C−C or C−N 7‐azaindole amidated derivatives. This amidation reaction shows an excellent controllability, which is believed to be dependent on catalyst system.

中文翻译:

7-氮杂吲哚酰胺化衍生物的合成:酰基叠氮化物作为氮源的有效利用

研究了酰基叠氮化物在过渡金属催化的直接CH H酰胺化反应中的双重行为。各种取代的酰基叠氮化物可与7-氮杂吲哚平稳反应,从而提供各种C-C或C-N 7-氮杂吲哚酰胺化衍生物。该酰胺化反应显示出优异的可控制性,据信这取决于催化剂体系。
更新日期:2018-01-16
down
wechat
bug