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Optimization of Disperse Blue 3 mineralization by UV-LED/FeTiO3 activated persulfate using response surface methodology
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-01-02 , DOI: 10.1016/j.jtice.2017.12.015
Jefferson E. Silveira , Elis Marina Turini Claro , Wendel S. Paz , Adriana S. Oliveira , Juan A. Zazo , Jose A. Casas

Response surface methodology based on Box-Behnken design (BBD) was successfully applied for the optimization of the UV-LED/FeTiO3 activated persulfate (PS) process. Disperse Blue 3 (DB3) azo dye oxidation was carried out in a quartz jacketed stirred batch reactor using 405 nm UV at 10 W/m−2 as radiation source. The effects of temperature, catalyst concentration and persulfate dose upon the total organic carbon (TOC) removal were investigated. Optimum operating conditions were found to be: ilmenite: 320 mg/L−1, PS: 1.56 g/L−1 and 67°C. Under these conditions, 96% mineralization was achieved. Ecotoxicity of the final effluent was evaluated using Aliivibrio fischeri bacteria, finding a negligible toxicity.



中文翻译:

使用响应面法优化UV-LED / FeTiO 3活化过硫酸盐对分散Blue 3矿化的作用

基于Box-Behnken设计(BBD)的响应面方法已成功应用于UV-LED / FeTiO 3活化过硫酸盐(PS)工艺的优化。在石英夹套搅拌的分批反应器中,使用405 nm UV以10 W / m -2作为辐射源,进行分散蓝3(DB3)偶氮染料的氧化。研究了温度,催化剂浓度和过硫酸盐剂量对去除总有机碳(TOC)的影响。发现最佳操作条件为:钛铁矿:320 mg / L -1,PS:1.56 g / L -1和67℃。在这些条件下,实现了96%的矿化。使用Aliivibrio fischeri细菌对最终废水的生态毒性进行了评估,发现毒性可以忽略不计。

更新日期:2018-01-02
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