Biologically inspired oxidation catalysis using metallopeptides,Dalton Transactions

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Biologically inspired oxidation catalysis using metallopeptides
Dalton Transactions ( IF 3.5 ) Pub Date : 2018-01-02 00:00:00 , DOI: 10.1039/c7dt03657d
Laia Vicens _{1,

2,

3,

4} , Miquel Costas _{1,

2,

3,

4}

Affiliation

The stereoselective oxidation of hydrocarbons is one of the most challenging reactions for synthetic chemists. However, this transformation is one of the most common reactions in nature. Metalloenzymes that catalyze this transformation are taken as inspiration for the development of new catalysts. There are several examples in the literature where either peptides or metal catalysts are used in the stereoselective oxidation reaction, but the synergistic combination of both systems is still a non-explored field. The use of metallopeptides in biologically inspired oxidation reactions is discussed in this perspective.

中文翻译：

使用金属肽的生物启发性氧化催化

碳氢化合物的立体选择性氧化是合成化学家最具挑战性的反应之一。但是，这种转化是自然界中最常见的反应之一。催化这种转变的金属酶被视为开发新催化剂的灵感。文献中有几个实例，其中在立体选择性氧化反应中使用了肽或金属催化剂，但是两个系统的协同结合仍是一个尚未探索的领域。从这个角度讨论了金属肽在生物学启发的氧化反应中的使用。

更新日期：2018-01-02

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