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A thermoresponsive supramolecular polymer gel from a heteroditopic calix[4]pyrrole
Chemical Communications ( IF 4.3 ) Pub Date : 2018-01-02 00:00:00 , DOI: 10.1039/c7cc08607e
Sana Amharar 1, 2, 3, 4 , Samet Yuvayapan 1, 2, 3, 4 , Abdullah Aydogan 1, 2, 3, 4
Affiliation  

Supramolecular polymerization of calix[4]pyrroles bearing tethered carboxylate functional groups was reported in the form of their tetrabutylammonium salts. At high concentrations one of the calix[4]pyrroles with a shorter linker between the calixpyrrole core and the carboxylate unit was found to give a thermoresponsive supramolecular polymer gel.

中文翻译:

异位杯[4]吡咯的热响应性超分子聚合物凝胶

以四丁基铵盐的形式报道了带有束缚的羧酸盐官能团的杯[4]吡咯的超分子聚合。在高浓度下,发现杯状[4]吡咯中的一个在杯状吡咯核与羧酸酯单元之间具有较短的连接基,从而产生热响应性超分子聚合物凝胶。
更新日期:2018-01-18
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