A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes,Angewandte Chemie International Edition

当前位置： X-MOL 学术 › Angew. Chem. Int. Ed. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2018-01-16 , DOI: 10.1002/anie.201712139
Lucie Norel _{1,

2} , Lucy E. Darago ₁ , Boris Le Guennic ₂ , Khetpakorn Chakarawet ₁ , Miguel I. Gonzalez ₁ , Jacob H. Olshansky ₁ , Stéphane Rigaut ₂ , Jeffrey R. Long ₁

Affiliation

The first dysprosium complexes with a terminal fluoride ligand are obtained as air‐stable compounds. The strong, highly electrostatic dysprosium–fluoride bond generates a large axial crystal‐field splitting of the J=15/2 ground state, as evidenced by high‐resolution luminescence spectroscopy and correlated with the single‐molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.

中文翻译：