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Formation of polyfluorofluorenes in the reactions of perfluoro-1,1-diphenylalkanes with antimony pentafluoride
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 2017-12-29 , DOI: 10.1016/j.jfluchem.2017.12.018
Tatyana V. Mezhenkova , Victor M. Karpov , Yaroslav V. Zonov

Perfluoro-1,1-diphenylethane heated with SbF5 at 130 °C with further treatment of the reaction mixture with HF-pyridine and then with water, gave perfluorinated 9‐methylfluorene and 9-methyl-1,2,3,4-tetrahydrofluorene. Perfluoro-1,1-diphenylpropane under similar conditions formed perfluoro-9-ethylfluorene and perfluoro-9,9-dimethyl-1,2,3,4-tetrahydrofluorene. When perfluoroisobutylbenzene was heated with pentafluorobenzene in SbF5 medium at 130 °C, with further treatment of the reaction mixture with HF-pyridine and then with water, perfluoro-9-isopropylfluorene was obtained. Perfluorodiphenylmethane heated with SbF5, after treatment of the reaction mixture with water, gave perfluorobenzophenone; perfluorofluorene or its derivatives were not found in the mixture.



中文翻译:

全氟-1,1-二苯基烷烃与五氟化锑反应中聚氟芴的形成

全氟-1,1-二苯乙烷与SbF 5在130°C加热,并将反应混合物先后用HF-吡啶和水处理,得到全氟9-甲基芴和9-甲基-1,2,3,4-四氢芴。全氟-1,1-二苯基丙烷在相似条件下形成全氟-9-乙基芴和全氟-9,9-二甲基-1,2,3,4-四氢芴。当将全氟异丁苯与五氟苯在SbF 5介质中于130°C加热时,先用HF-吡啶,然后用水进一步处理反应混合物,得到全氟-9-异丙基芴。用SbF 5加热的全氟二苯甲烷用水处理反应混合物后,得到全氟二苯甲酮。在混合物中未发现全氟芴或其衍生物。

更新日期:2017-12-29
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