当前位置: X-MOL 学术Chem. Phys. Lett. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Sulfur (VI) modified graphite carbon nitride nanosheets with chrysanthemum-like structure and enhanced photocatalytic activity
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2017-12-28 , DOI: 10.1016/j.cplett.2017.12.071
Lili Xie , Yunrong Dai , Yijing Zhou , Xin Chang , Lifeng Yin

Chrysanthemum-like sulfur (VI) modified graphite carbon nitride (s/g-C3N4) was synthesized by sulfuring and sonicating bulk g-C3N4 at 800 kHz. The sulfuring relaxed the interlayer force of g-C3N4, and the sonication constructed its chrysanthemum-like structure which enhances the separation of photo-generated carriers and photochemical response. Density functional calculation and diffusion reflection spectra (DRS) verified that sulfur (VI) modification shifted down the valence band edge of g-C3N4 and improved the redox potentials of g-C3N4. The photocatalytic degradation efficiency of 4-nitrophenol (10 mg L-1) by s/g-C3N4 was 49.3 times higher than that by bulk g-C3N4 under visible light irradiation (>400 nm).



中文翻译:

具有菊花状结构和增强的光催化活性的硫(VI)改性石墨碳氮化物纳米片

通过在800 kHz下对块状g -C 3 N 4进行硫化和超声处理,合成了类菊花硫(VI)改性的石墨碳氮化物(s / g -C 3 N 4)。硫化消除了g -C 3 N 4的层间力,并且超声处理构造了其菊花状结构,从而增强了光生载流子的分离和光化学反应。密度泛函计算和扩散反射光谱(DRS)验证了硫(VI)修饰向下移动了g -C 3 N 4的价带边缘并提高了g -C 3 N 4的氧化还原电位。s / g -C 3 N 4对4-硝基苯酚(10 mg L -1)在可见光(> 400 nm)下的光催化降解效率比本体g -C 3 N 4的光催化降解效率高49.3倍。

更新日期:2017-12-31
down
wechat
bug