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Plasma-catalyst hybrid reactor with CeO2/γ-Al2O3 for benzene decomposition with synergetic effect and nano particle by-product reduction
Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2017-12-28 , DOI: 10.1016/j.jhazmat.2017.12.064
Lingai Mao , Zhizong Chen , Xinyue Wu , Xiujuan Tang , Shuiliang Yao , Xuming Zhang , Boqiong Jiang , Jingyi Han , Zuliang Wu , Hao Lu , Tomohiro Nozaki

A dielectric barrier discharge (DBD) catalyst hybrid reactor with CeO2/γ-Al2O3 catalyst balls was investigated for benzene decomposition at atmospheric pressure and 30 °C. At an energy density of 37-40 J/L, benzene decomposition was as high as 92.5% when using the hybrid reactor with 5.0wt%CeO2/γ-Al2O3; while it was 10%-20% when using a normal DBD reactor without a catalyst. Benzene decomposition using the hybrid reactor was almost the same as that using an O3 catalyst reactor with the same CeO2/γ-Al2O3 catalyst, indicating that O3 plays a key role in the benzene decomposition. Fourier transform infrared spectroscopy analysis showed that O3 adsorption on CeO2/γ-Al2O3 promotes the production of adsorbed O2 and O22‒, which contribute benzene decomposition over heterogeneous catalysts. Nano particles as by-products (phenol and 1,4-benzoquinone) from benzene decomposition can be significantly reduced using the CeO2/γ-Al2O3 catalyst. H2O inhibits benzene decomposition; however, it improves CO2 selectivity. The deactivated CeO2/γ-Al2O3 catalyst can be regenerated by performing discharges at 100 oC and 192-204 J/L. The decomposition mechanism of benzene over CeO2/γ-Al2O3 catalyst was proposed.



中文翻译:

利用CeO等离子体催化剂混合反应堆2 /γ-Al系2 ö 3为苯与分解协同作用和纳米粒子的副产物减少

利用CeO电介质阻挡放电(DBD)催化剂混合反应堆2 /γ-Al系2 ö 3催化剂球进行了研究用于在大气压下分解苯和30℃。在37-40焦耳/升的能量密度,苯分解高达92.5%使用具有5.0重量%的CeO混合反应器时2 /γ-Al系2 ö 3 ; 当使用没有催化剂的普通DBD反应器时为10%-20%。使用混合反应堆苯分解几乎相同使用O 3催化剂反应器具有相同的CeO 2 /γ-Al系2 ö 3催化剂,表明ö 3在苯分解中起关键作用。傅里叶变换红外光谱分析表明,直径:3上的CeO吸附2 /γ-Al系2 ö 3促进产生吸附的O 2 -和O 2 2-,这有助于在非均相催化剂苯分解。纳米颗粒作为副产物从苯分解(苯酚与1,4-苯醌)可以使用的CeO被显著减少2 /γ-Al系2 ö 3催化剂。H 2 O抑制苯分解;但是,它提高了CO 2的选择性。失活的CeO 2 /γ-Al通过在100 o C和192-204 J / L下进行放电,可以再生2 O 3催化剂。苯在CeO分解机构2 /γ-Al系2 ö 3提出催化剂。

更新日期:2017-12-31
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