Abstract The voltammetry of electrochemically-irreversible and quasi-reversible reactions are investigated theoretically at a macroelectrode for the case of an applied cosine square-based potential waveform. The results reveal distinct features in the voltammograms which can be exploited to determine the electrochemical transfer coefficient, α, and the standard electrochemical rate constant, k0, of a reaction with high sensitivity.

中文翻译：

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具有非三角形波形的循环伏安法：电化学不可逆和准可逆系统

摘要 在施加基于余弦平方的电位波形的情况下，在宏观电极上从理论上研究了电化学不可逆和准可逆反应的伏安法。结果揭示了伏安图中的明显特征，可利用这些特征以高灵敏度确定反应的电化学转移系数 α 和标准电化学速率常数 k0。